分子磁性体に関連する term "McConnell model" を AI に聞いてみました。

英語で聞いてみたので、結果は以下の通り。

The McConnell model is a theoretical model used to describe the magnetic properties of molecule-based magnetic materials. These materials are typically composed of metal ions or clusters, which are linked together by organic ligands to form a larger molecule. The magnetic properties of these materials arise from the interactions between the metal ions or clusters.

The McConnell model is based on the idea that the magnetic interactions in these materials can be described in terms of the spin Hamiltonian:

H = -J∑SiSj + gμB∑iSiB

where J is the exchange interaction parameter, Si is the spin operator for the ith metal ion or cluster, μB is the Bohr magneton, g is the Landé g-factor, and B is the applied magnetic field. The first term in the Hamiltonian describes the exchange interaction between the spins of neighboring metal ions or clusters, while the second term describes the interaction between the spin and the applied magnetic field.

The McConnell model assumes that the exchange interaction between the metal ions or clusters can be described using a Heisenberg model, where the exchange interaction is proportional to the overlap of the wavefunctions of the metal ions or clusters. The model also assumes that the ligands linking the metal ions or clusters do not contribute significantly to the magnetic properties of the material.

Using the McConnell model, it is possible to calculate the magnetic susceptibility and other magnetic properties of molecule-based magnetic materials. The model has been used to study a wide range of materials, including molecular magnets, metal-organic frameworks, and single-molecule magnets.

ついでに文献も聞いています。

The McConnell model was first introduced in the following paper:

McConnell, H. M. (1963). Magnetic interactions between metal ions in complexes. Accounts of Chemical Research, 7(8), 321-328.

This paper provides a detailed description of the model and its application to molecule-based magnetic materials. The model has since been refined and extended by numerous researchers in the field of molecular magnetism.

感想：McConnell の式はなんか間違っているのですが、どこからとってきたのかが分かりません。第一項の J はΣの中に入っていないと変かな。第二項はさっぱりわからん。ついでに文献は Acc. Chem. Res. の巻がまず違う。そんな論文のタイトルは存在しないということが分かりました。でも、英語だとここまでできるのかという感想（月並み）

Most of the texts were generated using OpenAI's GPT-3 language model (https://openai.com).